The amount of evaporated water in the surface portion dA can
be expressed through the relationship:
dL = kv (psat – pv)
dA, where kv is the evaporation function index.
The following expression describes the amount of heat
(QD) removed from water during evaporation:
dQD = r dL (3), where r is the heat of vaporization.
In equilibrium conditions, there is a balance between the
amount of heat loss due to fluid evaporation and to the quantity of heat
(Qc) transferred to it by conduction: dQD = dQc
which written in terms of temperature leads to the following
expression:
r dL = G cp dt
while in terms of heat exchange surface, we have:
r [kv (psat –
pv)] dA = α (tG,DB-
tL1) dA (4)
Instead of the psat and pv pressure
functions, it's possible to calculate water quantity (dL) as a function of
water contained in air or specific humidity (x); this gives an immediate idea
of the amount of water vapor that is transferred to the air.
If pA and pV represent the
partial pressures due to the above-mentioned components, the total pressure of
the air is pT = pA + pV (Dalton);
since the steam is overheated and its behavior is very close to that of a
perfect gas, it's possible to apply the law PV = RT; meaning that for the two
components, after the appropriate steps, it's possible to describe water
content in saturated air (xsat) as x.
PMV = molecular weight of water vapor = 18
PMG = molecular weight of the dry air »29
It's thus possible to obtain the values of saturation and
water vapor pressure, respectively.
The simplified expressions have been written taking into
account that generally, and especially, in the temperature range where cooling
towers operate, the values pv and psat are
small compared to the value of the total pressure, where the constant
c is a function of the total pressure and of the molecular weights of the
components.
All this allows rewriting equation (4), which after
appropriate simplification becomes:
r [c kv (x sat - x)]
= α (tG,DB- tL)
i.e., introducing the overall coefficient of mass
transfer K = c (kV) in relation to the water content:
r (x sat - x) = (α / K) (tG,DB-
tL) (5)
then,
((tG,DB-tG,DB1) cp =
(x1 - x) r (6)
If we consider a channel of infinite length, we must attend
a full compensation between water and air to the complete saturation,
i.e., for which continues to be valid equation (6), hence:
(t-θe) c’p = (X’’e -
X) r (7)
when the temperature (θe ) and the
relative water content at saturation level (X’’e) are at fixed
values, i.e., values that are known and do not vary can be considered both the
specific heat of air (c’p). The evaporation heat (r): equation (7)
shows that the relationship between temperature and water content in air is
linear.
The temperature measured in air-saturated conditions, also
called wet-bulb temperature or adiabatic saturation (tWB), is the
limit temperature of water cooling.
The above content wants to illustrate that the cooling water
temperature for cooling towers cannot be lower than the wet-bulb temperature.
Therefore, the greater the difference in temperature between cooling water and
wet-bulb temperature (approach), determines a smaller cooling tower.
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